Sciency Words: Hydrogen

Hello, friends!  Welcome to Sciency Words, a special series here on Planet Pailly where we talk about the definitions and etymologies of scientific names and terms.  In today’s episode of Sciency Words, we’re talking about:

HYDROGEN

I want to start this with a personal story.  Imagine me, twenty years ago, fresh out of college with a degree in television and film production.  One of my first jobs was working for a company that made educational cartoons for children.  At one point, I ended up being assigned to a two minute animated music video about water.  The name of the video: “Water Can Never Be New.”

Now I’m no scientist.  I cannot call myself an expert (I’m just very enthusiastic about this subject).  And twenty years ago, I was even less of an expert than I am today.  Still, even way back then, I had a nagging suspicion that this “Water Can Never Be New” video was a lie.  Which brings me to the subject of today’s post: hydrogen.

Definition of hydrogen: Hydrogen is the very first element on the periodic table of elements.  Typically, hydrogen atoms consist of one proton orbited by one electron.  Molecular hydrogen consists of two hydrogen atoms bonded to each other.  Under Earth-like temperatures and Earth-like atmospheric pressure, hydrogen is a gas.  It’s also rather rare here on Earth; elsewhere in the universe, it’s extremely common.  In fact, hydrogen is by far the most common, most abundant chemical element in the universe.

Etymology of hydrogen: Hydrogen was first discovered in 1671 by British natural philosopher Robert Boyle.  Boyle referred to this new kind of air he discovered as “inflammable air,” because of how easily he could light it on fire.  Over a century later, French chemist Antoine Lavoisier found that burning “inflammable air” somehow produced water vapor as a byproduct.  Thus, Lavoisier changed the name of “inflammable air” to hydrogen, from two Greek words meaning “water” and “creation.”

It’s hard to imagine today just how much the discovery of hydrogen must have rocked the world of science (a.k.a. natural philosophy) back in the 17th and 18th Centuries.  Up until that point, the Aristotelian view of world had prevailed.  According to Aristotle, four elements—fire, earth, air, and water—were the fundamental building blocks of nature.  Then Robert Boyle comes along with a new kind of air (can we really call air a fundamental element if there are different kinds of it?), and Lavoisier subsequently demonstrates that you can use this new kind of air to make water (is water really a fundamental element if you can make it out of other stuff?).

Today, we know more about what happens when you light hydrogen gas on fire.  The heat energy from the flame causes hydrogen to react with oxygen, producing H2O molecules.  Water, in other words.  New water.  And, in fact, many chemical reactions involving hydrogen and oxygen-containing compounds will produce water molecules as a byproduct.  Due to the energy involved in these reactions, this new water may be too hot to form a liquid, but water vapor is still water (and it will condense into a liquid eventually, once it has time to cool off).

Of course, hydrogen does much more than help make new water molecules.  Hydrogen is the fuel that keeps the Sun shining.  It’s a necessary component in the organic compounds that make life as we know it possible, and hydrogen ions play an important role in acid-base chemistry (not counting Lewis acids and bases).  Given the wide variety of jobs that hydrogen does, you may wonder why we stick to using a name that means, simply, “water generator.”

But the discovery of hydrogen and its water generating ability helped upend some deeply entrenched and woefully inaccurate scientific ideas.  The name seems appropriate to me as a way to honor that moment in the history of science when the old Aristotelian view of nature really started to crumble.  It’s a shame more people don’t know about this story.  Maybe somebody should make an educational cartoon for children about it.

Sciency Words: Oxidation

Hello, friends, and welcome back to Sciency Words, a special series here on Planet Pailly where we talk about the definitions and etymologies of scientific terms.  Today on Sciency Words, we’re talking about:

OXIDATION

You may think of oxygen as something good and wholesome.  It’s what we breathe.  It gives us life.  How easily you forget all the other things oxygen can do.  It corrodes metals.  It degrades organic materials.  And under the right conditions, oxygen supports and perpetuates combustion reactions (a.k.a. fire).

French chemist Antoine Lavoisier usually gets credit for coining the words oxygen and oxidation.  He was the first to write about the principe oxygine (French for the acidifying principle).  The words oxygen and oxidation appeared soon afterwards in English translations of Lavoisier’s work, so maybe the English translators should get some of the credit too.

Anyway, oxidation originally referred to chemical reactions involving oxygen, specifically.  But then through a process of semantic generalization, the word oxidation came to refer to any chemical reaction similar to the kind of chemical reaction oxygen could cause.  Oxygen is no longer considered a necessary ingredient for oxidation, and some chemicals (i.e.: chlorine and fluorine) have turned out to be better oxidizers than oxygen.

So what actually happens when one chemical substance oxidizes another?  Well, oxygen and other strong oxidizing agents are greedy for electrons.  Oxidation is the act of stealing electrons from another chemical substance.  Or, if outright stealing doesn’t work, then oxidizing agents will try to form chemical bonds that allow them to “share” electrons—but it will be a highly unequal kind of sharing, one that does not favor the atoms that originally owned those electrons.

A whole lot of energy can be released in oxidation reactions.  That’s what makes them so destructive.  However, life on Earth has found ways to control the energy released by oxygen oxidation and put that energy to good use.  That’s why oxygen is generally thought of as something good and wholesome, even though it’s really one of the most dangerous and destructive chemicals in the world.

P.S.: It’s important to remember that whenever an oxidation reaction occurs, a reduction reaction also occurs.  And reduction is another Sciency Word with an interesting history.

Sciency Words: Oxygen

Hello, friends!  Welcome to Sciency Words, a special series here on Planet Pailly where we take a closer look at the definitions and etymologies of scientific terms.  Today on Sciency Words, we’re talking about:

OXYGEN

Earth.  Fire.  Air.  Water.  Only the Avatar can master all four elements.  Only the Avatar… or Antione-Laurent Lavoisier, the 18th Century French chemist.  As described in this article, Lavoisier originally intended to study each of the four elements in turn, starting with air.  But Lavoisier’s air research quickly “bent” the concept of the four elements so hard that the whole concept broke. And thus…

Lavoisier did not discover oxygen, but he did name it.  You see, when oxygen was first discovered in the early 1770’s, it was called “dephlogisticated air.”  That’s a mouthful of a name, but it made perfect sense to anyone who was familiar with the phlogiston theory of combustion.

Now I’m not going to waste your time explaining what phlogiston theory was, except to tell you that it was an updated-for-the-18th-Century version of the theory that fire is an element.  The important thing to know is that Lavoisier’s experiments on dephlogisticated air poked some pretty big holes in phlogiston theory, and so that theory had to be abandoned in favor of “oxygen theory.”

So where did the word oxygen come from?  Let me try to reconstruct Lavoisier’s thought process.  Among other things, Lavoisier found that burning stuff in “dephlogisticated air” tended to produce substances that were more acidic than the original reactants.  “Oxy” is Greek for acid.  So some sort of acid-generating process was occurring… an “oxy-genesis,” if you will.  Or “oxy-gen” for short!

The term Lavoisier actually used was principe oxygéne, meaning “the acidifying principle.”  The words oxygen and oxidation start appearing in English shortly thereafter, thanks mainly to translations of Lavoisier’s work.  But by that point, it was clear that oxygen was more than merely an acid-generating gas.  It had other properties too. Lavoisier demonstrated that oxygen played an important role in both combustion and animal respiration, as well as other natural processes like the rusting of iron.

But we’ll talk more about oxygen’s many abilities in next week’s episode of Sciency Words.

P.S.: Lavoisier also named hydrogen.  Burning “inflammable air” and “dephlogisticated air” together produced water.  “Hydro” is Greek for water.  So some sort of water-generating process was occurring… a “hydro-genesis,” if you will.  Or “hydro-gen” for short!

P.P.S.: And since you can make water by mixing two different kinds of air, water must not be an element.  Also, how can air truly be an element if there are different kinds of air? This whole four elements thing fell apart pretty quickly as Lavoisier continued his research.